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Tetramethylsilane (TMS) is used as a reference in NMR because:... | Filo
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SOLVED:The NMR spectrum of 2 -propenylmagnesium bromide in ether is shown in Figure 31-4 . With the aid of the discussion in Sections 9-10 C and 9-10 E and the knowledge that the CH2 resonance of ethylmagnesium bromide comes at 38  Hz upfield from tetramethylsilane, sketch the NMR spectrum you would expect for CH2=CHCH2 MgBr. Consider possible ways of reconciling your expected spectrum with the actual spectrum shown in Figure 31-4 . (Review Section 27-2 . )
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